Melamine Product Specification Sheet
Content
SECTION 1 – Product and Company Information Trade name: Chemical name: Melamine Chemical formula: C3H6N6
2, 4, 6-Triamino-1,3,5-triazine
Use of the substance /preparation
Used in the manufacture of resins and resin-based laminates, wood-based panels, coatings, molding powders, paints, adhesives, plastics, concrete plasticizers and flame retardants.
Company Information: Methanol Holdings (Trinidad) Limited Atlantic Avenue, Point Lisas Industrial Estate, Point Lisas, Couva, Trinidad and Tobago Telephone no. 1 868 636 2906 Fax no. 1 868 679 2553
Emergency telephone no.: Industrial Plant Services Ltd. Melamine Shift Supervisor 1 868 679 8626 Advice on Safety Data Sheet: [email protected]
SECTION 2 – Composition / Information on Ingredients Chemical characterization: Melamine 108-78-1 EINECS no. 203-615-4
Substance/product identification: CAS no.
SECTION 3 – Hazards Identification
Hazard symbols:
Not applicable
Human Health Hazards: Environmental Hazards: Physical/chemical Hazards:
Dust may cause minor irritation Based on data available for this product no hazardous properties are known Non-combustible. Possibility of explosion under dusty conditions
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 4 – First Aid Measures
Inhalation Remove affected person from the area of exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention. Skin contact Immediately flush skin with plenty of water for at least 15 minutes, removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing properly before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Ingestion DO NOT induce vomiting. If the victim is conscious and alert, give 2 – 4 cupfuls of water. Never give anything by mouth to an unconscious person. Seek immediate medical attention.
SECTION 5 – Fire-Fighting Measures
Suitable extinguishing media Extinguishing powder; Carbon dioxide; Alcohol- resistant foam Hazardous thermal decomposition and combustion products o o Melamine sublimates at temperatures above 350 C. At temperatures above 500 C ammonia is released. Special protective equipment for fire-fighter Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus with a full face-piece operated in positive pressure mode.
SECTION 6 – Accidental Release Measures
Personal precautions Remove persons to safety. Avoid creating dusty conditions and prevent wind dispersal. Use suitable protective clothing.
Methods for cleaning up/taking up Pick up mechanically and dispose of in designated, labeled waste container.
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 7 – Handling and Storage Handling No special measures necessary if stored and handled as prescribed. Avoid the formation and deposition of dust. Provide good ventilation of working area (local exhaust ventilations if necessary). Take precautionary measures against static charges. Keep away from sources of heat and ignition.
Advice on protection against fire and explosion This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. There is a slight risk of explosion if heated under confinement. Keep away from sources of heat and ignition. Storage Do not store together with: Acids or oxidizing agents. Keep in dry in a cool, well-ventilated place. DO NOT STACK MORE THAN 2 SUPERSACS HIGH
SECTION 8 – Exposure Control / Personal Protection Exposure limit values: NONE Personal protective equipment Respiratory protection Not necessary if area is well – ventilated. Use dust mask or other breathing apparatus if warranted. Hand protection In the case of intensive contact wear protective gloves made from PVC or PE. Eye protection Safety glasses Skin protection Light protective clothing General protective and hygiene measures Do not inhale dust. Clean skin thoroughly with soap and water after contact.
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 9 – Physical and Chemical Properties General information Physical State: Powder Color: White Changes in physical state Melting range Ignition temperature Vapor pressure Density Bulk density Solubility in water pH value Octanol/water partition coefficient (log Pow) SECTION 10 – Stability and Reactivity Conditions to avoid Reactions with strong oxidizing agents or acids Hazardous decomposition products Nitrous gases; Carbon monoxide and carbon dioxide; Ammonia; Hydrogen cyanide (HCN) Thermal decomposition No decomposition below 300 0C SECTION 11 – Toxicological Information Acute toxicity Acute oral toxicity LD50 3161 Species rat Irritant/corrosive effects mg/kg Molecular Weight: Odor: 126.13 Odorless
> 300 0C >600 0C 67 mbar – at 315 0C 1.57 g/cm3 - at 20 0C 550 - 750 kg/m3 appr. 3-5 g/l – at 20 0C 7-8 – at 20 0C (Concentration 3.2 g/l) -1.14 – at 25 0C - Method OECD 107
Irritant effect on skin Species rabbit Evaluation non irritant Irritant effect on eyes Species rabbit eye Evaluation slight irritant effect-does not require labeling Sensitization Species guinea pig Evaluation Non-sensitizing Effects after repeated or prolonged exposition (sub acute, sub-chronic, and chronic) Carcinogenicity Indications of possible carcinogenic effects in animal studies are available. Other information IARC Cancer Review: Group 3
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 12 – Ecological Information Eco-toxicity Fish toxicity LC50 >3000 g/m3 Daphnia toxicity EC50 2000 g/m3 Algae toxicity EC50 940 g/m3 Bacteria toxicity EC50 >10000 g/m3 Persistence and degradability Biodegradability Species: Poe cilia reticulate Species : Daphnia magna Species: Scenedesmus pannonicus Species: Pseudomonas putida Exposure: 96 h Exposure: 48 h Exposure: 4 d Exposure: 30 min
<20% Method: beaker test
Exposure: 20 d Evaluation: sparingly degradable
SECTION 13 – Disposal Considerations Product Waste must be disposed of in accordance with applicable environmental regulations. SECTION 14 – Transport Information Non – hazardous material as by defined by transport regulations. SECTION 15 – Regulatory Information US Federal and State Regulations: Pennsylvania RTK: Melamine Massachusetts RTK: Melamine New Jersey: Melamine United States Inventory (TSCA 8b): This material is listed or exempted United States Inventory (TSCA 12b): None of the chemicals are listed under TSCA 12B United States Inventory (TSCA Significant New Use Rule): None of the chemicals listed have a SNUR under TSCA. Other Regulations: EINECS: This product is on the European Inventory for Existing Commercial Chemical Substances Other Classifications: WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): R36/37/38- Irritating to eyes, respiratory system, and skin S24/25 – Avoid contact with skin and eyes S36/37/39 – Wear suitable protective clothing, gloves, and eye/face protection HMIS (USA): Health Hazard: 2 Fire Hazard: 1 Reactivity: 0 Personal Protection: E
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
National Fire Protection Association (U.S.A.): Health: 2 Flammability: 1 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab-coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Hazard symbols: NONE Council Directive 96/82/EC on the control of major- accident hazards involving dangerous substances Remarks: Annex1, part 1+2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10. SECTION 16 – Other Information Sources of key data used to compile the data in sheet: EC Directive 67/548/EC resp. 99/45/EC as amended in each case Regulation (EC) No 1907/2006 (REACH) as amended in each case. EC Directives 2003/39/EC, 2006/15/EC as amended in each case. National Threshold Limit Values of the corresponding countries as amended in each case. Transport regulations according to ADR, RID, IMDG, and IATA as amended in each case. The data sources used to determine physical, toxic and eco-toxic are indicated directly in the corresponding chapter. Prepared by: Methanol Holdings (Trinidad) Limited.
DISCLAIMER The information and recommendations herein are taken from data contained in independent, industry-recognized references and is believed to be accurate and represents the best information currently available to us. Methanol Holdings (Trinidad) Limited makes no representation or warranties, either expressed or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. Users should conduct their own investigations to determine the suitability of the information to their particular purpose. Accordingly, Methanol Holdings (Trinidad) Limited will not be responsible for loss or damages resulting from use of or reliance upon this information.
Date of Issue / Date of Revision: October 14, 2011
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
2, 4, 6-Triamino-1,3,5-triazine
Use of the substance /preparation
Used in the manufacture of resins and resin-based laminates, wood-based panels, coatings, molding powders, paints, adhesives, plastics, concrete plasticizers and flame retardants.
Company Information: Methanol Holdings (Trinidad) Limited Atlantic Avenue, Point Lisas Industrial Estate, Point Lisas, Couva, Trinidad and Tobago Telephone no. 1 868 636 2906 Fax no. 1 868 679 2553
Emergency telephone no.: Industrial Plant Services Ltd. Melamine Shift Supervisor 1 868 679 8626 Advice on Safety Data Sheet: [email protected]
SECTION 2 – Composition / Information on Ingredients Chemical characterization: Melamine 108-78-1 EINECS no. 203-615-4
Substance/product identification: CAS no.
SECTION 3 – Hazards Identification
Hazard symbols:
Not applicable
Human Health Hazards: Environmental Hazards: Physical/chemical Hazards:
Dust may cause minor irritation Based on data available for this product no hazardous properties are known Non-combustible. Possibility of explosion under dusty conditions
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 4 – First Aid Measures
Inhalation Remove affected person from the area of exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention. Skin contact Immediately flush skin with plenty of water for at least 15 minutes, removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing properly before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Ingestion DO NOT induce vomiting. If the victim is conscious and alert, give 2 – 4 cupfuls of water. Never give anything by mouth to an unconscious person. Seek immediate medical attention.
SECTION 5 – Fire-Fighting Measures
Suitable extinguishing media Extinguishing powder; Carbon dioxide; Alcohol- resistant foam Hazardous thermal decomposition and combustion products o o Melamine sublimates at temperatures above 350 C. At temperatures above 500 C ammonia is released. Special protective equipment for fire-fighter Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus with a full face-piece operated in positive pressure mode.
SECTION 6 – Accidental Release Measures
Personal precautions Remove persons to safety. Avoid creating dusty conditions and prevent wind dispersal. Use suitable protective clothing.
Methods for cleaning up/taking up Pick up mechanically and dispose of in designated, labeled waste container.
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 7 – Handling and Storage Handling No special measures necessary if stored and handled as prescribed. Avoid the formation and deposition of dust. Provide good ventilation of working area (local exhaust ventilations if necessary). Take precautionary measures against static charges. Keep away from sources of heat and ignition.
Advice on protection against fire and explosion This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. There is a slight risk of explosion if heated under confinement. Keep away from sources of heat and ignition. Storage Do not store together with: Acids or oxidizing agents. Keep in dry in a cool, well-ventilated place. DO NOT STACK MORE THAN 2 SUPERSACS HIGH
SECTION 8 – Exposure Control / Personal Protection Exposure limit values: NONE Personal protective equipment Respiratory protection Not necessary if area is well – ventilated. Use dust mask or other breathing apparatus if warranted. Hand protection In the case of intensive contact wear protective gloves made from PVC or PE. Eye protection Safety glasses Skin protection Light protective clothing General protective and hygiene measures Do not inhale dust. Clean skin thoroughly with soap and water after contact.
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 9 – Physical and Chemical Properties General information Physical State: Powder Color: White Changes in physical state Melting range Ignition temperature Vapor pressure Density Bulk density Solubility in water pH value Octanol/water partition coefficient (log Pow) SECTION 10 – Stability and Reactivity Conditions to avoid Reactions with strong oxidizing agents or acids Hazardous decomposition products Nitrous gases; Carbon monoxide and carbon dioxide; Ammonia; Hydrogen cyanide (HCN) Thermal decomposition No decomposition below 300 0C SECTION 11 – Toxicological Information Acute toxicity Acute oral toxicity LD50 3161 Species rat Irritant/corrosive effects mg/kg Molecular Weight: Odor: 126.13 Odorless
> 300 0C >600 0C 67 mbar – at 315 0C 1.57 g/cm3 - at 20 0C 550 - 750 kg/m3 appr. 3-5 g/l – at 20 0C 7-8 – at 20 0C (Concentration 3.2 g/l) -1.14 – at 25 0C - Method OECD 107
Irritant effect on skin Species rabbit Evaluation non irritant Irritant effect on eyes Species rabbit eye Evaluation slight irritant effect-does not require labeling Sensitization Species guinea pig Evaluation Non-sensitizing Effects after repeated or prolonged exposition (sub acute, sub-chronic, and chronic) Carcinogenicity Indications of possible carcinogenic effects in animal studies are available. Other information IARC Cancer Review: Group 3
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
SECTION 12 – Ecological Information Eco-toxicity Fish toxicity LC50 >3000 g/m3 Daphnia toxicity EC50 2000 g/m3 Algae toxicity EC50 940 g/m3 Bacteria toxicity EC50 >10000 g/m3 Persistence and degradability Biodegradability Species: Poe cilia reticulate Species : Daphnia magna Species: Scenedesmus pannonicus Species: Pseudomonas putida Exposure: 96 h Exposure: 48 h Exposure: 4 d Exposure: 30 min
<20% Method: beaker test
Exposure: 20 d Evaluation: sparingly degradable
SECTION 13 – Disposal Considerations Product Waste must be disposed of in accordance with applicable environmental regulations. SECTION 14 – Transport Information Non – hazardous material as by defined by transport regulations. SECTION 15 – Regulatory Information US Federal and State Regulations: Pennsylvania RTK: Melamine Massachusetts RTK: Melamine New Jersey: Melamine United States Inventory (TSCA 8b): This material is listed or exempted United States Inventory (TSCA 12b): None of the chemicals are listed under TSCA 12B United States Inventory (TSCA Significant New Use Rule): None of the chemicals listed have a SNUR under TSCA. Other Regulations: EINECS: This product is on the European Inventory for Existing Commercial Chemical Substances Other Classifications: WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): R36/37/38- Irritating to eyes, respiratory system, and skin S24/25 – Avoid contact with skin and eyes S36/37/39 – Wear suitable protective clothing, gloves, and eye/face protection HMIS (USA): Health Hazard: 2 Fire Hazard: 1 Reactivity: 0 Personal Protection: E
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
National Fire Protection Association (U.S.A.): Health: 2 Flammability: 1 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab-coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Hazard symbols: NONE Council Directive 96/82/EC on the control of major- accident hazards involving dangerous substances Remarks: Annex1, part 1+2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10. SECTION 16 – Other Information Sources of key data used to compile the data in sheet: EC Directive 67/548/EC resp. 99/45/EC as amended in each case Regulation (EC) No 1907/2006 (REACH) as amended in each case. EC Directives 2003/39/EC, 2006/15/EC as amended in each case. National Threshold Limit Values of the corresponding countries as amended in each case. Transport regulations according to ADR, RID, IMDG, and IATA as amended in each case. The data sources used to determine physical, toxic and eco-toxic are indicated directly in the corresponding chapter. Prepared by: Methanol Holdings (Trinidad) Limited.
DISCLAIMER The information and recommendations herein are taken from data contained in independent, industry-recognized references and is believed to be accurate and represents the best information currently available to us. Methanol Holdings (Trinidad) Limited makes no representation or warranties, either expressed or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. Users should conduct their own investigations to determine the suitability of the information to their particular purpose. Accordingly, Methanol Holdings (Trinidad) Limited will not be responsible for loss or damages resulting from use of or reliance upon this information.
Date of Issue / Date of Revision: October 14, 2011
2 Northpoint Drive, Suite 975 Houston, TX 77060 QC.010
Rev. 002
Phone: 832.448.7161 Fax: 832.448.7175 Issue Date: 10/2011
